Syntax:
ALTER [ONLINE | OFFLINE] [IGNORE] TABLE tbl_name
    alter_specification [, alter_specification] ...

alter_specification:
    table_option ...
  | ADD [COLUMN] col_name column_definition
        [FIRST | AFTER col_name ]
  | ADD [COLUMN] (col_name column_definition,...)
  | ADD {INDEX|KEY} [index_name]
        [index_type] (index_col_name,...) [index_option] ...
  | ADD [CONSTRAINT [symbol]] PRIMARY KEY
        [index_type] (index_col_name,...) [index_option] ...
  | ADD [CONSTRAINT [symbol]]
        UNIQUE [INDEX|KEY] [index_name]
        [index_type] (index_col_name,...) [index_option] ...
  | ADD FULLTEXT [INDEX|KEY] [index_name]
        (index_col_name,...) [index_option] ...
  | ADD SPATIAL [INDEX|KEY] [index_name]
        (index_col_name,...) [index_option] ...
  | ADD [CONSTRAINT [symbol]]
        FOREIGN KEY [index_name] (index_col_name,...)
        reference_definition
  | ALTER [COLUMN] col_name {SET DEFAULT literal | DROP DEFAULT}
  | CHANGE [COLUMN] old_col_name new_col_name column_definition
        [FIRST|AFTER col_name]
  | MODIFY [COLUMN] col_name column_definition
        [FIRST | AFTER col_name]
  | DROP [COLUMN] col_name
  | DROP PRIMARY KEY
  | DROP {INDEX|KEY} index_name
  | DROP FOREIGN KEY fk_symbol
  | DISABLE KEYS
  | ENABLE KEYS
  | RENAME [TO] new_tbl_name
  | ORDER BY col_name [, col_name] ...
  | CONVERT TO CHARACTER SET charset_name [COLLATE collation_name]
  | [DEFAULT] CHARACTER SET [=] charset_name [COLLATE [=] collation_name]
  | DISCARD TABLESPACE
  | IMPORT TABLESPACE
  | partition_options
  | ADD PARTITION (partition_definition)
  | DROP PARTITION partition_names
  | COALESCE PARTITION number
  | REORGANIZE PARTITION [partition_names INTO (partition_definitions)]
  | ANALYZE PARTITION partition_names
  | CHECK PARTITION partition_names
  | OPTIMIZE PARTITION partition_names
  | REBUILD PARTITION partition_names
  | REPAIR PARTITION partition_names
  | REMOVE PARTITIONING

index_col_name:
    col_name [(length)] [ASC | DESC]

index_type:
    USING {BTREE | HASH | RTREE}

index_option:
    KEY_BLOCK_SIZE [=] value
  | index_type
  | WITH PARSER parser_name
  | COMMENT 'string'

ALTER TABLE enables you to change the structure of an existing table.
For example, you can add or delete columns, create or destroy indexes,
change the type of existing columns, or rename columns or the table
itself. You can also change the comment for the table and type of the
table.

URL: http://dev.mysql.com/doc/refman/5.1/en/alter-table.html

